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112-EN, General section

Surface treatment of metals and plastic

Resúmen

This document describes the best available techniques for surface treatment of metals and plastics. Substitution possibilities for EDTA, PFOS, zinc cyanide, copper cyanide and hexavalent chromium are mentioned.

  1. Compuestos perfluorados (PFC)

    Núm. CAS  Núm. EC  Núm. Index 
  2. Acido edético

    Núm. CAS 60-00-4 Núm. EC 200-449-4 Núm. Index 607-429-00-8
  3. Cromo hexavalente

    Núm. CAS 18540-29-9 Núm. EC  Núm. Index 

Otro tipo de alternativa

The document also describes non-chemical alternatives to many processes

Fiabilidad de la información

Evidencia de evaluación: hay evidencia de una evaluación oficial (positiva) del proceso de sustitución


Evaluación de peligros

Hexavalent chromium compounds are included in SUBSPORT´s database of hazardous substances.

» Comprobar la base de datos de sustancias de acuerdo a los criterios de selección de SUBSPORT (SDSC)

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Descripción del proceso de sustitución

In this document the chemicals used in installation for surface treatment for metals and plastics using an electrolytical or chemical process are assessed in order to describe the best available techniques (BAT).  SUBSPORT will only shortly mention the substitutions in the document. For more information please look in “Further information”.  The document can be obtained for free from the  link.

The following substitutions are mentioned:

EDTA

Chelating agents such as EDTA and NTA are often used in degreasers and etchants used for printed circuit boards. They may be replaced by biodegradable ones – for example based on gluconic acid.

PFOS

Perfluorooctans sulphonate is used as a foam suppressant and surfactant especially in the prevention of mists in hexavalent chromium electroplating and in alkali non-cyanide baths. The document mentions, that substitutes should be available for anodising, but no specific chemical is described.

Zinc cyanide

Instead of using zinc cyanide solutions the best available technique is acid zinc. This gives an optimum energy efficiency and reduced environmental emissions. Where metal distribution is important alkali cyanide-free zinc is the best available technique. Some products may contain PFOS.

Copper cyanide

Copper cyanide is used in strike plating on steel and zinc die casts. It can be substituted by acid copper, which is the choice in Germany. Pyrophosphate copper can also be used, but has limited applications. No alternatives are found for brass and bronze.

Hexavalent chromium

For decorative chromium plating hexavalent chromium can be replaced by trivalent chromium. Sealers and phosphochromate finishers can contain hexavalent chromium. Many of these can be replaced with non-Cr 6 solutions based on for example silanes, zirconium and titanium.

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Evaluación del caso/sustitución

It is not possible for SUBSPORT to evaluate the alternatives, as the information is not specified enough in the document.

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Otras soluciones

Más información

http://www.ineris.fr/ippc/sites/default/files/files/stm_bref_0806.pdf

Otros idiomas disponibles


Quién proporcionó la información

Tipo de suministrador de la infromación
Autoridad

Contacto 

Fuente de la publicación

Reference documents on best available techniques for surface treatment of metals and plastics. European Commission, August 2006.

Tipo de publicación y disponibilidad del documento 

Documento original: pinchar aquí


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